Saturday, July 12, 2014

UPSC Civil Services Main Examination 2014 Syllabus Paper VII: Chemistry-II

1. Delocalised Covalent Bonding: Aromaticity, anti-aromaticity; annulenes, azulenes, tropolones, fulvenes, sydnones.

2. (i) Reaction Mechanisms: General methods (both kinetic and non-kinetic) of study of mechanism of organic reactions: isotopic method, cross-over experiment, intermediate trapping, stereochemistry;
energy of activation; thermodynamic control and kinetic control of reactions.
(ii) Reactive Intermediates: Generation, geometry, stability and reactions of carbonium ions and carbanions, free radicals, carbenes, benzynes and nitrenes.
(iii) Substitution Reactions: SN1, SN2 and SNi mechanisms; neighbouring group participation; electrophilic and nucleophilic reactions of aromatic compounds including heterocyclic compounds–pyrrole, furan, thiophene and indole.
(iv) Elimination Reactions: E1, E2 and E1cb mechanisms; orientation in E2 reactions–Saytzeff and Hoffmann;
pyrolytic syn elimination – Chugaev and Cope eliminations.
(v) Addition Reactions: Electrophilic addition to C=C and C=C; nucleophilic addition to C=0, C=N, conjugated olefins and carbonyls.
(vi) Reactions and Rearrangements: (a) Pinacol-pinacolone, Hoffmann, Beckmann, Baeyer–Villiger,  Favorskii, Fries, Claisen, Cope, Stevens and Wagner-Meerwein rearrangements.
(b) Aldol condensation, Claisen condensation, Dieckmann, Perkin, Knoevenagel, Witting, Clemmensen, Wolff-Kishner, Cannizzaro and von Richter reactions; Stobbe, benzoin and acyloin condensations;
Fischer indole synthesis, Skraup synthesis, Bischler-Napieralski, Sandmeyer, Reimer-Tiemann and
Reformatsky reactions.


3. Pericyclic Reactions: Classification and examples; Woodward-Hoffmann rules – electrocyclic reactions,
cycloaddition reactions [2+2 and 4+2] and sigmatropic shifts [1, 3; 3, 3 and 1, 5] FMO approach.

4. (i) Preparation and Properties of Polymers: Organic polymers–polyethylene, polystyrene, polyvinyl chloride, teflon, nylon, terylene, synthetic and natural rubber. (ii) Biopolymers: Structure of proteins,
DNA and RNA.

5. Synthetic Uses of Reagents: OsO4, HIO4, CrO3, Pb(OAc)4, SeO2, NBS, B2H6, Na-Liquid NH3, LiAlH4, NaBH4, n-BuLi and MCPBA.

6. Photochemistry: Photochemical reactions of simple organic compounds, excited and ground states,
singlet and triplet states, Norrish-Type I and Type II reactions.

7. Spectroscopy: Principle and applications in structure elucidation: (i) Rotational: Diatomic molecules; isotopic substitution and rotational constants. (ii) Vibrational: Diatomic molecules, linear triatomic molecules, specific frequencies of functional groups in polyatomic molecules. (iii) Electronic: Singlet and triplet states;
N→π* and ππ*→ transitions; application to conjugated double bonds and conjugated
carbonyls–Woodward-Fieser rules; Charge transfer spectra. (iv) Nuclear Magnetic Resonance (1H
NMR): Basic principle; chemical shift and spin-spin interaction and coupling constants. (v) Mass Spectrometry: Parent peak, base peak, metastable peak, McLafferty rearrangement.

UPSC Civil Services Main Examination 2014 Syllabus of more subjects browse from the links below:

UPSC Civil Services Main Examination 2014 Syllabus: Zoology Paper-II
UPSC Civil Services Examination 2014 Syllabus: Zoology Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Statistics Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Statistics Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Sociology-II
UPSC Civil Services Main Examination 2014 Syllabus: Sociology Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Public Administration Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Public Administration Paper-I
UPSC Civil Services Main Examination 2014 Syllabus Psychology-II
UPSC Civil Services Main Examination 2014 Syllabus: Psychology Paper-I
UPSC Civil Services Main Examination 2014 Syllabus Political Science and International Relations Paper-I
UPSC Civil Services Examination 2014 Syllabus: Political Science and International Relations (PS&IR) Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Physics Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Physics Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Philosophy Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Philosophy Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Medical Science-II
UPSC Civil Services Main Examination 2014 Syllabus: Medical Science Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Mechanical Engineering Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Mechanical Engineering Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Mathematics Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Mathematics Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Management Paper-II
UPSC Civil Services Examination 2014 Syllabus: Management Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Urdu Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Urdu Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Telugu Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Telugu Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Tamil Paper-II
UPSC Civil Services Examination 2014 Syllabus: Tamil Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Sindhi Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Sindhi Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Sindhi Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Santhali Paper-II
UPSC Civil Services Examination 2014 Syllabus: Santhali Paper-I
UPSC Civil Services Examination 2014 Syllabus: Sanskrit Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Sanskrit Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Punjabi Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Punjabi Paper-I
UPSC Civil Services Main Examination Syllabus: Oriya Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Oriya Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Nepali Paper-II
UPSC Civil Services Main Examination 2014: Nepali Paper-I
UPSC Civil Services Main Examination 2014 Syllabus Marathi Paper-II
UPSC Civil Services Main Examination 2014 Syllabus Marathi Paper-I
UPSC Civil Services Main Examination 2014 Syllabus Manipuri Paper-II
UPSC Civil Services Examination 2014 Syllabus Manipuri Paper-I
UPSC Civil Services Examination 2014 Syllabus: Malyalam Paper-II
UPSC Civil Services Main Examination 2014 Syllabus Malayalam Paper-I
UPSC Civil Services Main Examination 2014 Syllabus Maithili-II
UPSC Civil Services Main Examination 2014 Syllabus Maithili-I
UPSC Civil Services Main Examination 2014 Syllabus Konkani-II
UPSC Civil Services Main Examination 2014 Syllabus Konkani-I
UPSC Civil Services Main Examination 2014 Syllabus Kashmiri-II
UPSC Civil Service Main Examination 2014 Syllabus Kashmiri-I
UPSC Civil Services Main Examination 2014 Syllabus Kannada-II
UPSC Civil Services Main Examination 2014 Syllabus Kannada-I
UPSC Civil Services Main Examination 2014 Syllabus Hindi-II
UPSC Civil Services Main Examination 2014 Syllabus Hindi-I
UPSC Civil Services Main Examination 2014 Syllabus Gugarati-II
UPSC Civil Services Main Examination 2014 Syllabus Gujarati Paper I
UPSC Civil Services Main Examination 2014 Syllabus English-II
UPSC Civil Services Examination 2014 Syllabus English - I
UPSC Civil Services Main Examination 2014 Syllabus: Dogri-II
UPSC Civil Services Main Examination 2014 Syllabus Dogri Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Bodo-II
UPSC Civil Services Main Examination 2014 Syllabus: Bodo-I
UPSC Civil Services Main Examination 2014 Syllabus: Bengali Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Bengali Paper I
UPSC Civil Services Main Exam 2014 Syllabus: Assamese-II
UPSC Civil Services Main Exam 2014 Syllabus: Assamese-I
UPSC Civil Services Main Examination 2014 Syllabus: Law-II
UPSC Civil Services Main Examination 2014 Syllabus: Law-I
UPSC Civil Services Main Examination 2014 Syllabus: History-II
UPSC Civil Services Main Examination 2014 Syllabus: History-I
UPSC Civil Services Main Examination 2014 Syllabus: Geology-II
UPSC Civil Services Main Examination 2014 Syllabus: Geology-I
UPSC Civil Services Main Examination 2014 Syllabus: Geography-II
UPSC Civil Service Main Exam Syllabus 2014: Geography-I
UPSC Civil Services Main Examination 2014 Syllabus Electrical Engineering-II
UPSC Civil Services Main Examination 2014 Syllabus Electrical Engineering-I
UPSC Civil Services Main Exam 2014 Syllabus Paper VII: Economics-II
UPSC Civil Services Main Exam 2014 Syllabus: Paper VI: Economics-I
UPSC Civil Services Main Examination 2014 Syllabus Paper VII: Commerce and Accountancy-II
UPSC Civil Services Main Examination 2014 Syllabus Paper VI: Commerce and Accountancy-I
UPSC Civil Services Main Examination 2014 Syllabus Paper VII: Civil Engineering-II
UPSC Civil Services Main Examination 2014 Syllabus Paper VI: Civil Engineering-I
UPSC Civil Services Main Examination 2014 Syllabus Paper VII: Chemistry-II
UPSC Civil Services Main Examination Syllabus Paper VI: Chemistry-I
UPSC Civil Services Main Examination 2014 Syllabus Paper VII: Botany-II
UPSC Civil Services Main Examination 2014 Syllabus Paper VI: Botany-I
UPSC Civil Services Main Examination 2014 Syllabus Paper VII: Anthropology-II
UPSC Civil Services Main Examination 2014: Syllabus Paper VI: Anthropology-I
UPSC Civil Services Main Examination 2014 Syllabus Paper VII
UPSC Civil Services Main Examination 2014: Syllabus Paper VI
UPSC Civil Services Main Examination 2014: Syllabus Paper VII: Agriculture-II
UPSC Civil Services Main Examination 2014: Syllabus Paper VI: Agriculture-I
UPSC Civil Services Main Examination 2014 Syllabus: Paper-V: General Studies-IV
UPSC Civil Services Main Examination 2014 Syllabus: Paper-IV: General Studies-III
UPSC Civil Services Main Examination 2014 Syllabus: Paper-III: General Studies-II
UPSC Civil Services Main Examination 2014 Syllabus: Paper-II: General Studies-I
UPSC Civil Services Main Examination 2014 Syllabus: Paper-I: Essay
UPSC Civil Services Main Examination 2014 Syllabus: Indian Language and English

More Useful Articles about UPSC Civil Services Examination 2014

UPSC Civil Services Examination 2014
UPSC Civil Services Exam Pattern 2014
Bird's Eye View: UPSC Civil Services Main Examination 2014 Subjects and Question Paper
Level of Question Papers in Civil Service Main Examination 2014
Criteria of Negative Marking in UPSC Civil Services Examination 2014
UPSC Civil Services Preliminary Exam Syllabus 2014
Download E-Admit Card: UPSC Civil Services Preliminary Examination 2014

UPSC Civil Services Prelims Exam Previous Years Question Papers and Answers

No comments:

Post a Comment

Thanks for visiting this website. Your feedback are important to us. Please note we only approve genuine comments!

Submit your Career Questions below!

Name

Email *

Message *