Saturday, July 12, 2014

UPSC Civil Services Main Examination Syllabus Paper VI: Chemistry-I

1. Atomic Structure: Heisenberg’s uncertainty principle, Schrodinger wave equation (time independent);
Interpretation of wave function, particle in one-dimensional box, quantum numbers, hydrogen atom wave functions; Shapes of s, p and d orbitals.

2. Chemical Bonding: Ionic bond, characteristics of ionic compounds, lattice energy, Born-Haber cycle;
covalent bond and its general characteristics, polarities of bonds in molecules and their dipole moments; Valence bond theory, concept of resonance and resonance energy; Molecular orbital theory (LCAO method); bonding in H2+, H2, He2+ to Ne2, NO, CO, HF, and CN–; Comparison of valence bond and molecular orbital theories, bond order, bond strength and bond length.


3. Solid State:  Crystal systems; Designation of crystal faces, lattice structures and unit cell; Bragg’s law; X-ray diffraction by crystals; Close packing, radius ratio rules, calculation of some limiting radius ratio values;
Structures of NaCl, ZnS, CsCl and CaF2; Stoichiometric and nonstoichiometric defects, impurity defects, semi-conductors.

4. The Gaseous State and Transport Phenomenon: Equation of state for real gases, intermolecular
interactions and critical phenomena and liquefaction of gases, Maxwell’s distribution of speeds, intermolecular collisions, collisions on the wall and effusion; Thermal conductivity and viscosity of ideal gases.

5. Liquid State: Kelvin equation; Surface tension and surface energy, wetting and contact angle, interfacial tension and capillary action.

6. Thermodynamics: Work, heat and internal energy; first law of thermodynamics. Second law of  thermodynamics; entropy as a state function, entropy changes in various processes, entropy–reversibility
and irreversibility, Free energy functions; Thermodynamic equation of state; Maxwell relations; Temperature, volume and pressure dependence of U, H, A, G, Cp and Cv α and β; J-T effect and inversion temperature; criteria for equilibrium, relation between equilibrium constant and thermodynamic quantities; Nernst heat theorem, introductory idea of third law of thermodynamics.

7. Phase Equilibria and Solutions: Clausius-Clapeyron equation; phase diagram for a pure substance; phase equilibria in binary systems, partially miscible liquids–upper and lower critical solution temperatures; partial molar quantities, their significance and determination; excess thermodynamic functions and their determination.

8. Electrochemistry: Debye-Huckel theory of strong electrolytes and Debye-Huckel limiting Law for various equilibrium and transport properties. Galvanic cells, concentration cells; electrochemical series, measurement of e.m.f. of cells and its applications fuel cells and batteries. Processes at electrodes; double layer at
the interface; rate of charge transfer, current density; overpotential; electro-analytical techniques: Polarography, amperometry, ion selective electrodes and their uses.

9. Chemical Kinetics: Differential and integral rate equations for zeroth, first, second and fractional order
reactions; Rate equations involving reverse, parallel, consecutive and chain reactions; branching chain and explosions; effect of temperature and pressure on rate constant; Study of fast reactions by stop-flow and relaxation methods; Collisions and transition state theories.

10. Photochemistry: Absorption of light; decay of excited state by different routes; photochemical reactions
between hydrogen and halogens and their quantum yields.

11. Surface Phenomena and Catalysis: Absorption from gases and solutions on solid adsorbents, Langmuir and B.E.T. adsorption isotherms; determination of surface area, characteristics and mechanism of reaction on heterogeneous catalysts.

12. Bio-inorganic Chemistry: Metal ions in biological systems and their role in ion transport across the membranes (molecular mechanism), oxygenuptake proteins, cytochromes and ferredoxins.

13. Coordination Compounds: (i) Bonding theories of metal complexes; Valence bond theory, crystal field theory and its modifications; applications of theories in the explanation of magnetism and electronic spectra of metal complexes. (ii) Isomerism in coordination compounds; IUPAC nomenclature of coordination
compounds; stereochemistry of complexes with 4 and 6 coordination numbers; chelate effect and polynuclear complexes; trans effect and its theories; kinetics of substitution reactions in square-planer complexes; thermodynamic and kinetic stability of complexes. (iii) EAN rule, Synthesis structure and
reactivity of metal carbonyls; carboxylate anions, carbonyl hydrides and metal nitrosyl compounds.
(iv) Complexes with aromatic systems, synthesis, structure and bonding in metal olefin complexes, alkyne complexes and cyclopentadienyl complexes; coordinative unsaturation, oxidative addition reactions,
insertion reactions, fluxional molecules and their characterization; Compounds with metal-metal bonds and
metal atom clusters.

14. Main Group Chemistry: Boranes, borazines, phosphazenes and cyclic phosphazene, silicates and silicones, Interhalogen compounds; Sulphur – nitrogen compounds, noble gas compounds.

15. General Chemistry of ‘f’ Block Elements: Lanthanides and actinides; separation, oxidation states, magnetic and spectral properties; lanthanide contraction.

UPSC Civil Services Main Examination 2014 Syllabus of more subjects browse from the links below:

UPSC Civil Services Main Examination 2014 Syllabus: Zoology Paper-II
UPSC Civil Services Examination 2014 Syllabus: Zoology Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Statistics Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Statistics Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Sociology-II
UPSC Civil Services Main Examination 2014 Syllabus: Sociology Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Public Administration Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Public Administration Paper-I
UPSC Civil Services Main Examination 2014 Syllabus Psychology-II
UPSC Civil Services Main Examination 2014 Syllabus: Psychology Paper-I
UPSC Civil Services Main Examination 2014 Syllabus Political Science and International Relations Paper-I
UPSC Civil Services Examination 2014 Syllabus: Political Science and International Relations (PS&IR) Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Physics Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Physics Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Philosophy Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Philosophy Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Medical Science-II
UPSC Civil Services Main Examination 2014 Syllabus: Medical Science Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Mechanical Engineering Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Mechanical Engineering Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Mathematics Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Mathematics Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Management Paper-II
UPSC Civil Services Examination 2014 Syllabus: Management Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Urdu Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Urdu Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Telugu Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Telugu Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Tamil Paper-II
UPSC Civil Services Examination 2014 Syllabus: Tamil Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Sindhi Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Sindhi Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Sindhi Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Santhali Paper-II
UPSC Civil Services Examination 2014 Syllabus: Santhali Paper-I
UPSC Civil Services Examination 2014 Syllabus: Sanskrit Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Sanskrit Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Punjabi Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Punjabi Paper-I
UPSC Civil Services Main Examination Syllabus: Oriya Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Oriya Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Nepali Paper-II
UPSC Civil Services Main Examination 2014: Nepali Paper-I
UPSC Civil Services Main Examination 2014 Syllabus Marathi Paper-II
UPSC Civil Services Main Examination 2014 Syllabus Marathi Paper-I
UPSC Civil Services Main Examination 2014 Syllabus Manipuri Paper-II
UPSC Civil Services Examination 2014 Syllabus Manipuri Paper-I
UPSC Civil Services Examination 2014 Syllabus: Malyalam Paper-II
UPSC Civil Services Main Examination 2014 Syllabus Malayalam Paper-I
UPSC Civil Services Main Examination 2014 Syllabus Maithili-II
UPSC Civil Services Main Examination 2014 Syllabus Maithili-I
UPSC Civil Services Main Examination 2014 Syllabus Konkani-II
UPSC Civil Services Main Examination 2014 Syllabus Konkani-I
UPSC Civil Services Main Examination 2014 Syllabus Kashmiri-II
UPSC Civil Service Main Examination 2014 Syllabus Kashmiri-I
UPSC Civil Services Main Examination 2014 Syllabus Kannada-II
UPSC Civil Services Main Examination 2014 Syllabus Kannada-I
UPSC Civil Services Main Examination 2014 Syllabus Hindi-II
UPSC Civil Services Main Examination 2014 Syllabus Hindi-I
UPSC Civil Services Main Examination 2014 Syllabus Gugarati-II
UPSC Civil Services Main Examination 2014 Syllabus Gujarati Paper I
UPSC Civil Services Main Examination 2014 Syllabus English-II
UPSC Civil Services Examination 2014 Syllabus English - I
UPSC Civil Services Main Examination 2014 Syllabus: Dogri-II
UPSC Civil Services Main Examination 2014 Syllabus Dogri Paper-I
UPSC Civil Services Main Examination 2014 Syllabus: Bodo-II
UPSC Civil Services Main Examination 2014 Syllabus: Bodo-I
UPSC Civil Services Main Examination 2014 Syllabus: Bengali Paper-II
UPSC Civil Services Main Examination 2014 Syllabus: Bengali Paper I
UPSC Civil Services Main Exam 2014 Syllabus: Assamese-II
UPSC Civil Services Main Exam 2014 Syllabus: Assamese-I
UPSC Civil Services Main Examination 2014 Syllabus: Law-II
UPSC Civil Services Main Examination 2014 Syllabus: Law-I
UPSC Civil Services Main Examination 2014 Syllabus: History-II
UPSC Civil Services Main Examination 2014 Syllabus: History-I
UPSC Civil Services Main Examination 2014 Syllabus: Geology-II
UPSC Civil Services Main Examination 2014 Syllabus: Geology-I
UPSC Civil Services Main Examination 2014 Syllabus: Geography-II
UPSC Civil Service Main Exam Syllabus 2014: Geography-I
UPSC Civil Services Main Examination 2014 Syllabus Electrical Engineering-II
UPSC Civil Services Main Examination 2014 Syllabus Electrical Engineering-I
UPSC Civil Services Main Exam 2014 Syllabus Paper VII: Economics-II
UPSC Civil Services Main Exam 2014 Syllabus: Paper VI: Economics-I
UPSC Civil Services Main Examination 2014 Syllabus Paper VII: Commerce and Accountancy-II
UPSC Civil Services Main Examination 2014 Syllabus Paper VI: Commerce and Accountancy-I
UPSC Civil Services Main Examination 2014 Syllabus Paper VII: Civil Engineering-II
UPSC Civil Services Main Examination 2014 Syllabus Paper VI: Civil Engineering-I
UPSC Civil Services Main Examination 2014 Syllabus Paper VII: Chemistry-II
UPSC Civil Services Main Examination Syllabus Paper VI: Chemistry-I
UPSC Civil Services Main Examination 2014 Syllabus Paper VII: Botany-II
UPSC Civil Services Main Examination 2014 Syllabus Paper VI: Botany-I
UPSC Civil Services Main Examination 2014 Syllabus Paper VII: Anthropology-II
UPSC Civil Services Main Examination 2014: Syllabus Paper VI: Anthropology-I
UPSC Civil Services Main Examination 2014 Syllabus Paper VII
UPSC Civil Services Main Examination 2014: Syllabus Paper VI
UPSC Civil Services Main Examination 2014: Syllabus Paper VII: Agriculture-II
UPSC Civil Services Main Examination 2014: Syllabus Paper VI: Agriculture-I
UPSC Civil Services Main Examination 2014 Syllabus: Paper-V: General Studies-IV
UPSC Civil Services Main Examination 2014 Syllabus: Paper-IV: General Studies-III
UPSC Civil Services Main Examination 2014 Syllabus: Paper-III: General Studies-II
UPSC Civil Services Main Examination 2014 Syllabus: Paper-II: General Studies-I
UPSC Civil Services Main Examination 2014 Syllabus: Paper-I: Essay
UPSC Civil Services Main Examination 2014 Syllabus: Indian Language and English

More Useful Articles about UPSC Civil Services Examination 2014

UPSC Civil Services Examination 2014
UPSC Civil Services Exam Pattern 2014
Bird's Eye View: UPSC Civil Services Main Examination 2014 Subjects and Question Paper
Level of Question Papers in Civil Service Main Examination 2014
Criteria of Negative Marking in UPSC Civil Services Examination 2014
UPSC Civil Services Preliminary Exam Syllabus 2014
Download E-Admit Card: UPSC Civil Services Preliminary Examination 2014

UPSC Civil Services Prelims Exam Previous Years Question Papers and Answers

No comments:

Post a Comment

Thanks for visiting this website. Your feedback are important to us. Please note we only approve genuine comments!

Submit your Career Questions below!

Name

Email *

Message *